Oh man, this is something I think about a lot!
1. The Melancholy of Haruhi Suzumiya (Kyon)
2. Clannad (Youhei Sunohara)
3. Gurren Lagann (Simon or Rossiu)
4. Spice and Wolf (Lawrence Craft)
5. Sekirei (Minato)
I actually have a dub of Kyon's opening monologue in the works, so its sort of like a mini-dream come true for me hehe! I have a demo for my voice on my page and I'd like to hear some opinions on what characters I could do well. Give it a look! I would appreciate it!